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UN 3218: Nitrates, inorganic, aqueous solution, n.o.s.

Class 5.1, oxidizing substances, packing group II and III: the UN containers that may carry it under ADR 2025, the largest of each, and its limited quantity.

UN 3218 covers nitrates, inorganic, aqueous solution, n.o.s. in 2 entries of the Dangerous Goods List: Class 5.1, oxidizing substances, packing groups II and III. The packing group on your safety data sheet sets the container: UN jerricans of up to 60 L in every packing group, drums of up to 250 L in every packing group and IBCs of up to 3,000 L in packing groups II and III.

What class and packing group is UN 3218?

Proper shipping nameClassPacking groupLimited quantityPacking instruction
NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.5.1II1 LP504, IBC02
NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.5.1III5 LP504, IBC02, R001

Class 5.1 covers oxidizing substances: they need not burn themselves, but they give off oxygen that makes other material burn (ADR 2.2.51). Hydrogen peroxide solutions are classed by their strength.

Packing group I means high danger, II medium danger and III low danger (ADR 2.1.1.3). The group sets how strong the container must be: the UN mark shows X for packing group I, Y for II and Z for III, and a higher level covers the lower groups.

N.o.s. stands for not otherwise specified: a generic entry for a substance that has no entry of its own by name. For most n.o.s. entries the transport document adds the technical name of the hazardous component in brackets after the proper shipping name (ADR 3.1.2.8).

Performance level against packing groupA UN mark with X covers packing groups I, II and III; Y covers II and III; Z covers III only. Group I Group II Group III X X: suitable for Group I✓ X: suitable for Group II✓ X: suitable for Group III✓ Y Y: not suitable for Group I✕ Y: suitable for Group II✓ Y: suitable for Group III✓ Z Z: not suitable for Group I✕ Z: not suitable for Group II✕ Z: suitable for Group III✓
UN 3218 has entries in packing groups II and III: each needs the mark for its own group.

Which UN containers may carry UN 3218?

Each entry below shows the UN container types its packing instruction allows and the largest of each. Read the entry whose name matches section 14 of your safety data sheet.

UN 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

Container typeUN codesLargest allowedStatus
Jerrican, closed head3A1, 3H1, 3B160 L Permitted
Jerrican, removable head3A2, 3H2, 3B260 L Permitted
Drum, closed head1A1, 1H1, 1B1250 L Permitted
Drum, removable head1A2, 1H2, 1B2250 L Permitted
Plastic receptacle in a steel drum6HA1250 L Permitted
IBC31A, 31B, 31N, 31H1, 31H2, 31HZ13,000 L Permitted
Containers this entry may useContainers this entry may use
Jerrican, closed head
3A1 3H1 3B160 L
Jerrican, removable head
3A2 3H2 3B260 L
Drum, closed head
1A1 1H1 1B1250 L
Drum, removable head
1A2 1H2 1B2250 L
Plastic receptacle in a steel drum
6HA1250 L
IBC
31A 31B 31N3,000 L

These are the sizes the packing instruction allows. The container must also resist the liquid (4.1.1.2): chemical compatibility by liquid

UN 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.

Container typeUN codesLargest allowedStatus
Jerrican, closed head3A1, 3H1, 3B160 L Permitted
Jerrican, removable head3A2, 3H2, 3B260 L Permitted
Drum, closed head1A1, 1H1, 1B1250 L Permitted
Drum, removable head1A2, 1H2, 1B2250 L Permitted
Plastic receptacle in a steel drum6HA1250 L Permitted
IBC31A, 31B, 31N, 31H1, 31H2, 31HZ13,000 L Permitted
Containers this entry may useContainers this entry may use
Jerrican, closed head
3A1 3H1 3B160 L
Jerrican, removable head
3A2 3H2 3B260 L
Drum, closed head
1A1 1H1 1B1250 L
Drum, removable head
1A2 1H2 1B2250 L
Plastic receptacle in a steel drum
6HA1250 L
IBC
31A 31B 31N3,000 L

Our containers for this entry

Largest container for UN 3218, packing group III In packing group III, UN 3218 may travel in a UN jerrican of up to 60 L, a drum of up to 250 L or an IBC of up to 3,000 L. LARGEST CONTAINER FOR UN 3218, PACKING GROUP III Jerrican, closed head 60 L Drum, closed head 250 L Drum, removable head 250 L IBC 3,000 L
Single packagings under P504 and IBCs under IBC02, ADR 2025.

Can UN 3218 go in a plastic jerrican?

Yes. P504 lists plastic jerricans (3H1) for UN 3218 up to 60 L in packing group III, with a UN mark showing X, Y or Z.

Two more rules apply. The container must resist the liquid (ADR 4.1.1.2), so check the material against the substance before you fill. A plastic drum or jerrican for dangerous goods may be used for five years from its date of manufacture (ADR 4.1.1.15); steel has no such limit.

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What is the limited quantity for UN 3218?

It depends on the entry: 1 L in packing group II, 5 L in packing group III. The figures are column 7a of ADR 2025 Table A.

Under ADR chapter 3.4, a liquid in inner packagings no larger than that figure travels under reduced rules. The combination packaging may weigh up to 30 kg gross (20 kg on a shrink-wrapped tray), and it carries the limited quantity mark in place of the hazard labels.

From safety data sheet to container, UN 3218Section 14 of the safety data sheet gives UN 3218 and its packing group. The group sets the UN mark, and the packing instruction sets the container and its size. SDS section 14
UN 3218, class 5.1, packing group III
Packing group
III: the UN mark must show X, Y or Z
Instruction
P504 and IBC02
Containers
Jerrican to 60 L, drum to 250 L and IBC to 3,000 L

ADR limited quantities and the 1,000-point rule · ADR 1,000-point calculator

UN 3218 by sea, by air and in the US

ADR covers road transport in Europe, and RID rail uses the same list. By sea the IMDG Code has its own Dangerous Goods List, and by air the ICAO Technical Instructions and the IATA Dangerous Goods Regulations do. The class and packing group of UN 3218 normally match across them, but the packing instructions and the limits differ, so check the list for the mode you ship by.

In the US, the Hazardous Materials Table in 49 CFR 172.101 applies, and some materials carry an NA number there in place of a UN number. US rules call a UN-marked container specification packaging.

UN specification packaging · Dangerous goods transport · Packing groups explained

UN numbers related to UN 3218

UN numberNameClassPacking groups
UN 2014Hydrogen peroxide solution, 20% to 60%5.1II
UN 2984Hydrogen peroxide solution, 8% to 20%5.1III
UN 3149Hydrogen peroxide and peroxyacetic acid mixture5.1II
UN 3210Chlorates, inorganic, aqueous solution, n.o.s.5.1II, III
UN 3214Permanganates, inorganic, aqueous solution, n.o.s.5.1II
UN 3216Persulphates, inorganic, aqueous solution, n.o.s.5.1III

Where Fortitude21 fits

Fortitude21 makes UN-certified steel and plastic jerricans, certified per design type and made under quality assurance the competent authority accepts, plus pails and the spill pallets and bunds a store needs. The cards above match our range to each entry by UN code; where a card says to ask, we confirm the certificate for that design before you order.

Common questions

What is UN 3218?

UN 3218 is the UN number for nitrates, inorganic, aqueous solution, n.o.s.: Class 5.1, oxidizing substances, packing group II and III. In packing group III it may travel in a UN jerrican of up to 60 L, a drum of up to 250 L or an IBC of up to 3,000 L.

What hazard class is UN 3218?

Class 5.1, oxidizing substances. Class 5.1 covers oxidizing substances: they need not burn themselves, but they give off oxygen that makes other material burn (ADR 2.2.51). Hydrogen peroxide solutions are classed by their strength.

What packing group is UN 3218?

It depends on the entry: UN 3218 has 2 entries across packing groups II and III. Use the packing group in section 14 of the safety data sheet.

Can UN 3218 go in an IBC?

Yes, in packing group II and III: the entry lists IBC02, which allows metal, rigid plastics and composite IBCs of up to 3,000 L.

What is the limited quantity for UN 3218?

It depends on the entry: 1 L in packing group II, 5 L in packing group III. The figures are column 7a of ADR 2025 Table A.

References

The standards and regulations this page relies on, at their issuing body. Where a market rule is named here, check the current revision before you specify against it.

Data: ADR 2025 Table A as published in RID 2025 by OTIF, read on 6 October 2026, through the same engine as our UN number packaging finder. Check the current list before you ship.

Need containers for UN 3218?

Send the UN number, the packing group and the size. We reply with the design certified for it, the plant named on its certificate, and a price.

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